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The left diagram shows the deviated order, 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p. Follow the arrows from the top 1s 2s 2p 3s 3p. Follow the arrows from the top 1s 2s 2p 3s 3p. A fter the 3p sublevel it would seem logical that the 3d sublevel should be the next lowest in energy.

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Electron configurations have the format: 1s 2 2s 2 2p 6. The first number is the principal quantum number (n) and the letter represents the value of l (angular momentum quantum number; 1 = s, 2 = p, 3 = d and 4 = f) for the orbital, and the superscript number tells you how many electrons are in that orbital.

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Orbital Filling Diagrams •Each box represents an orbital which can hold a max of 2 e- •Aufbau principal –each electron occupies the lowest energy orbital available; German for "build up" •Electrons are notated with an arrow –Up arrow goes first then, down arrow –Arrows represent the opposing spin of electrons 5.2 Quantum Theory & The Atom

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For the orbital diagrams: We will use the short form, but show the actual orbitals, where each orbital picture is represented by a horizontal line. Bi : 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 4p 6 5s 2 4d 10 5p 6 6s 2 4f 14 5d 10 6p 3,

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